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Chin. Opt. Lett.
 Home  List of Issues    Issue 07 , Vol. 10 , 2012    10.3788/COL201210.071602

Effect of P2O5 addition on the structural and spectroscopic properties of sodium aluminosilicate glass
Jia Ding1;2, Youkuo Chen1, Wei Chen1, Lili Hu1, G. Boulon
1 Key Laboratory of Materials for High Power Laser, [Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences], Shanghai 201800, China
2 [Graduate University of Chinese Academy of Sciences], Beijing 100049, China
3 Physical Chemistry of Luminescence Materials, [University of Lyon], UMR CNRS 5620, Villeurbanne 69622, France

Chin. Opt. Lett., 2012, 10(07): pp.071602

Keywords(OCIS Code): 160.2750  160.5960  

The structural and spectroscopic properties of Na2O-Al2O3-SiO2-xP2O5 glasses (x=0 to 7 mol%) are investigated. Both Raman and IR spectra reveal that discrete phosphate species ([PO4]^{-3}, [PO3O_{1/2}]^{-2}) with low polymerization degree can be formed in the silicate glass. These phosphate structures scavenge non-bridging oxygen ions and cations from the silicate network, resulting in an increase of the glass transition temperature. According to the Judd-Ofelt intensity parameters (\Omega2;\Omega4;\Omega6) of Er3+, the asymmetry of local environment around Er3+ becomes higher, and the bond covalency between Er3+ and O^{2-} decreases after P2O5 is introduced. In the emission spectra, photoluminescence intensity increases with increasing P2O5 concentration and the spectra are inhomogeneously broadened, revealing that the ligand electric field around Er3+ is dramatically changed, and the glass matrix becomes disordered.

Copyright: © 2003-2012 . This is an open-access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.

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Posted online:2012/3/28

Get Citation: Jia Ding, Youkuo Chen, Wei Chen, Lili Hu, G. Boulon, "Effect of P2O5 addition on the structural and spectroscopic properties of sodium aluminosilicate glass," Chin. Opt. Lett. 10(07), 071602(2012)



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